@Article{GaefkeBoteFerrReze:2007:EfFuAl,
author = "Gaefke, C. B. and Botelho, E. C. and Ferreira, Neiden{\^e}i Gomes
and Rezende, Mirabel Cerqueira",
affiliation = "IAE/CTA and IAE/CTA and {Instituto Nacional de Pesquisas Espaciais
(INPE)} and IAE/CTA",
title = "Effect of furfuryl alcohol addition on the cure of furfuryl
alcohol resin used in the glassy carbon manufacture",
journal = "Journal of Applied Polymer Science",
year = "2007",
volume = "106",
number = "4",
pages = "2274--2281",
month = "Nov.",
keywords = "reticulated vitreous carbon, furfuryl alcohol resin, thermal
analyses, rheological analyses.",
abstract = "Glassy carbon can be manufactured practically without pores, named
Monolithic Vitreous Carbon (MVC) or presenting up to 98% in
transport pore volume, foam form, denominated Reticulated Vitreous
Carbon (RVC). The glassy carbon processing is affected by some
processing parameters, among them it can be cited the resin
viscosity. The present work involves the optimization of RVC
manufacture by monitoring the polyurethane (PU) foam impregnation
with furfuryl alcohol resin with different viscosity values, which
were obtained by dilution of the resin with different amounts of
furfuryl alcohol. The resin samples used in the PU impregnation
were characterized by thermal and rheological analyses. These
results were correlated with scanning electron microscopy
observations and compression test results of the impregnated
polyurethane foam. The results show that the rheological behavior
of the resin has significant influence on the polymerization step,
affecting the homogeneity of impregnated foam and, consequently,
its final properties, mainly the mechanical one. The impregnated
foam prepared with the furfuryl alcohol resin diluted with 10% of
furfuryl alcohol (eta = 11.4 Pa s) showed higher compression
values (0.26 MPa).",
doi = "10.1002/app.26938",
url = "http://dx.doi.org/10.1002/app.26938",
issn = "0021-8995 and 1097-4628",
language = "en",
targetfile = "26938_ftp.pdf",
urlaccessdate = "07 maio 2024"
}